An explosive substance or mixture is a solid or liquid substance or mixture of substances which is in itself capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to cause damage to the surroundings. Pyrotechnic substances are included even when they do not evolve gases.
A pyrotechnic substance or mixture is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonative self-sustaining exothermic chemical reactions.
An unstable explosive is an explosive substance or mixture which is thermally unstable and/or too sensitive for normal handling, transport and use.
An intentional explosive is a substance, mixture or article which is manufactured with a view to producing a practical, explosive or pyrotechnic effect. (CLP, Annex I, 2.1.1.2).
● | Unstable explosive | Unst. Expl.: H200 |
● | Explosive, division 1.1 | Expl. 1.1: H201 |
● | Explosive, division 1.2 | Expl. 1.2: H202 |
● | Explosive, division 1.3 | Expl. 1.3: H203 |
● | Explosive, division 1.4 | Expl. 1.4: H204 |
● | Explosive, division 1.5 | Expl. 1.5: H205 |
● | Explosive, division 1.6 | Expl. 1.6 |
Flammable gas means a gas or gas mixture having a flammable range with air at 20 ºC and a standard pressure of 101.3 kPa.
A pyrophoric gas means a flammable gas that is liable to ignite spontaneously in air at a temperature of 54 ºC or below.
A chemically unstable gas means a flammable gas that is able to react explosively even in the absence of air or oxygen (CLP, Annex I, 2.2.1).
● | Flammable gas, category 1 | Flam. Gas 1: H220 |
● | Flammable gas, category 1A | Flam. Gas 1A: H220 |
● | Flammable gas, category 1B | Flam. Gas 1B: H221 |
● | Flammable gas, category 2 | Flam. Gas 2: H221 |
● | Pyrophoric gas | Pyr. Gas: H220 |
● | Pyrophoric gas | Pyr. Gas: H232 |
● | Chemically unstable gas, category A | Chem. Unst. Gas A: H220 |
● | Chemically unstable gas, category A | Chem. Unst. Gas A: H230 |
● | Chemically unstable gas, category B | Chem. Unst. Gas B: H220 |
● | Chemically unstable gas, category B | Chem. Unst. Gas B: H231 |
Aerosols, this means aerosol dispensers, are any non-refillable receptacles made of metal, glass or plastics and containing a gas compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder, and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in a gas, as a foam, paste or powder or in a liquid state or in a gaseous state. (CLP, Annex I, 2.3.1).
● | Aerosol, category 1 | Aerosol 1: H222 |
● | Aerosol, category 1 | Aerosol 1: H229 |
● | Aerosol, category 2 | Aerosol 2: H223 |
● | Aerosol, category 2 | Aerosol 2: H229 |
● | Aerosol, category 3 | Aerosol 3: H229 |
Oxidising gas means any gas or gas mixture which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does. (CLP, Annex I, 2.4.1).
● | Oxidising gas, category 1 | Ox. Gas 1: H270 |
Gases under pressure are gases which are contained in a receptacle at a pressure of 200 kPa (gauge) or more at 20 ºC, or which are liquefied or liquefied and refrigerated. They comprise compressed gases, liquefied gases, dissolved gases and refrigerated liquefied gases. (CLP, Annex I, 2.5.1).
● | Gas under pressure | Press. Gas |
● | Gas under pressure, compressed gas | Press. Gas (Comp.): H280 |
● | Gas under pressure, liquefied gas | Press. Gas (Liq.): H280 |
● | Gas under pressure, refrigerated liquefied gas | Press. Gas (Ref. Liq.): H281 |
● | Gas under pressure, dissolved gas | Press. Gas (Diss.): H280 |
Flammable liquid means a liquid having a flash point of not more than 60 ºC. (CLP, Annex I, 2.6.1).
● | Flammable liquid, category 1 | Flam. Liq. 1: H224 |
● | Flammable liquid, category 2 | Flam. Liq. 2: H225 |
● | Flammable liquid, category 3 | Flam. Liq. 3: H226 |
A flammable solid means a solid which is readily combustible, or may cause or contribute to fire through friction. Readily combustible solids are powdered, granular, or pasty substances or mixtures which are dangerous if they can be easily ignited by brief contact with an ignition source, such as a burning match, and if the flame spreads rapidly. (CLP, Annex I, 2.7.1).
● | Flammable solid, category 1 | Flam. Sol. 1: H228 |
● | Flammable solid, category 2 | Flam. Sol. 2: H228 |
Self-reactive substances or mixtures are thermally unstable liquid or solid substances or mixtures liable to undergo a strongly exothermic decomposition even without participation of oxygen (air). This definition excludes substances and mixtures classified according to this Part as explosives, organic peroxides or as oxidising. A self-reactive substance or mixture is regarded as possessing explosive properties when in laboratory testing the formulation is liable to detonate, to deflagrate rapidly or to show a violent effect when heated under confinement. (CLP, Annex I, 2.8.1).
● | Self-reactive substance or mixture, type A | Self-react. A: H240 |
● | Self-reactive substance or mixture, type B | Self-react. B: H241 |
● | Self-reactive substance or mixture, type C | Self-react. C: H242 |
● | Self-reactive substance or mixture, type D | Self-react. D: H242 |
● | Self-reactive substance or mixture, type E | Self-react. E: H242 |
● | Self-reactive substance or mixture, type F | Self-react. F: H242 |
● | Self-reactive substance or mixture, type G | Self-react. G |
Pyrophoric liquid means a liquid substance or mixture which, even in small quantities, is liable to ignite within five minutes after coming into contact with air. (CLP, Annex I, 2.9.1).
● | Pyrophoric liquid, category 1 | Pyr. Liq. 1: H250 |
Pyrophoric solid means a solid substance or mixture which, even in small quantities, is liable to ignite within five minutes after coming into contact with air. (CLP, Annex I, 2.10.1).
● | Pyrophoric solid, category 1 | Pyr. Sol. 1: H250 |
A self-heating substance or mixture is a liquid or solid substance or mixture, other than a pyrophoric liquid or solid, which, by reaction with air and without energy supply, is liable to self-heat; this substance or mixture differs from a pyrophoric liquid or solid in that it will ignite only when in large amounts (kilograms) and after long periods of time (hours or days). Self-heating of a substance or a mixture is a process where the gradual reaction of that substance or mixture with oxygen (in the air) generates heat. If the rate of heat production exceeds the rate of heat loss, then the temperature of the substance or mixture will rise which, after an induction time, may lead to self-ignition and combustion. (CLP, Annex I, 2.11.1).
● | Self-heating substance or mixture, category 1 | Self-heat. 1: H251 |
● | Self-heating substance or mixture, category 2 | Self-heat. 2: H252 |
Substances or mixtures which, in contact with water, emit flammable gases means solid or liquid substances or mixtures which, by interaction with water, are liable to become spontaneously flammable or to give off flammable gases in dangerous quantities. (CLP, Annex I, 2.12.1).
● | Substance or mixture which in contact with water emits flammable gas, category 1 | Water-react. 1: H260 |
● | Substance or mixture which in contact with water emits flammable gas, category 2 | Water-react. 2: H261 |
● | Substance or mixture which in contact with water emits flammable gas, category 3 | Water-react. 3: H261 |
Oxidising liquid means a liquid substance or mixture which, while in itself not necessarily combustible, may, generally by yielding oxygen, cause, or contribute to, the combustion of other material. (CLP, Annex I, 2.13.1).
● | Oxidising liquid, category 1 | Ox. Liq. 1: H271 |
● | Oxidising liquid, category 2 | Ox. Liq. 2: H272 |
● | Oxidising liquid, category 3 | Ox. Liq. 3: H272 |
Oxidising solid means a solid substance or mixture which, while in itself is not necessarily combustible, may, generally by yielding oxygen, cause, or contribute to, the combustion of other material. (CLP, Annex I, 2.14.1).
● | Oxidising solid, category 1 | Ox. Sol. 1: H271 |
● | Oxidising solid, category 2 | Ox. Sol. 2: H272 |
● | Oxidising solid, category 3 | Ox. Sol. 3: H272 |
Organic peroxides means liquid or solid organic substances which contain the bivalent -O-O- structure and may be considered derivatives of hydrogen peroxide, where one or both of the hydrogen atoms have been replaced by organic radicals. The term organic peroxide includes organic peroxide mixtures (formulations) containing at least one organic peroxide. Organic peroxides are thermally unstable substances or mixtures, which can undergo exothermic self-accelerating decomposition. In addition, they can have one or more of the following properties:
(i) be liable to explosive decomposition;
(ii) burn rapidly;
(iii) be sensitive to impact or friction;
(iv) react dangerously with other substances.
An organic peroxide is regarded as possessing explosive properties when in laboratory testing the mixture (formulation) is liable to detonate, to deflagrate rapidly or to show a violent effect when heated under confinement. (CLP, Annex I, 2.15.1).
● | Organic peroxide, type A | Org. Perox. A: H240 |
● | Organic peroxide, type B | Org. Perox. B: H241 |
● | Organic peroxide, type C | Org. Perox. C: H242 |
● | Organic peroxide, type D | Org. Perox. D: H242 |
● | Organic peroxide, type E | Org. Perox. E: H242 |
● | Organic peroxide, type F | Org. Perox. F: H242 |
● | Organic peroxide, type G | Org. Perox. G |
A substance or a mixture that is corrosive to metals means a substance or a mixture which by chemical action will materially damage, or even destroy, metals. (CLP, Annex I, 2.16.1).
● | Substance or mixture corrosive to metals, category 1 | Met. Corr. 1: H290 |
Desensitised explosives are solid or liquid explosive substances or mixtures which are phlegmatised to suppress their explosive properties in such a manner that they do not mass explode and do not burn too rapidly and therefore may be exempted from the hazard class "Explosives". (CLP, Annex I, 2.17.1).
● | Desensitised explosive, category 1 | Desen. Expl. 1: H206 |
● | Desensitised explosive, category 2 | Desen. Expl. 2: H207 |
● | Desensitised explosive, category 3 | Desen. Expl. 3: H207 |
● | Desensitised explosive, category 4 | Desen. Expl. 4: H208 |